Tripropylene

Tripropylene

Tripropylene

Chemical compound


Tripropylene, also known as propylene trimer, is usually sold as a mixture of structural isomers of nonene.[2] This mixture is obtained by oligomerization of propene:

3 C3H6 → C9H18
Quick Facts Identifiers, Properties ...

In this process, two double bonds are lost and one is retained as illustrated by the isomer shown in the figure. The reaction is catalyzed by acids, such as polyphosphoric acid.[3] A variety of catalysts have been explored.[4] The reaction proceeds via the formation of a carbocation ((CH3)2CH+), which attacks another propylene unit, generating a new carbocation, etc. This kind of process affords mixtures (C3H6)n.

Like other alkenes, propylene trimer is used as an alkylating agent. A number of surfactants and lubricants are produced by alkylation of aromatic substrates.

See also


References

  1. Tripropylene MSDS, chemexper.net
  2. G. R. Lappin, L. H. Nemec, J. D. Sauer, J. D. Wagner "Olefins, Higher" in Kirk-Othmer Encyclopedia of Chemical Technology, 2010. doi:10.1002/0471238961.1512050612011616.a01.pub2
  3. Johan A. Martens, Wim H. Verrelst, Georges M. Mathys, Stephen H. Brown, Pierre A. Jacobs "Tailored Catalytic Propene Trimerization over Acidic Zeolites with Tubular Pores" Angewandte Chemie International Edition Angewandte Chemie International Edition 2005, Volume 44, Issue 35, pages 5687–5690. doi:10.1002/anie.200463045

Share this article:

This article uses material from the Wikipedia article Tripropylene, and is written by contributors. Text is available under a CC BY-SA 4.0 International License; additional terms may apply. Images, videos and audio are available under their respective licenses.