Thiophosphoryl_iodide

Thiophosphoryl iodide

Thiophosphoryl iodide

Chemical compound

Thiophosphoryl iodide is an inorganic compound with the formula PSI3.[1]

Quick Facts Names, Identifiers ...

Preparation

Thiophosphoryl iodide can be prepared by reacting phosphorus triiodide with sulfur in carbon disulfide at 10–15 °C in the dark for several days.[1][2]

Attempts to synthesise PSI3 by the reaction of lithium iodide with thiophosphoryl bromide lead to the mixed thiophosphoryl halides PSBr2I and PSBrI2 instead.[3]

References

  1. [1]
    Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. pp. 501–503. ISBN 978-0-08-037941-8.
  2. [2]
    Arthur D. F. Toy (1975). The Chemistry of Phosphorus. Permanon Texts in Inorganic Chemistry. Vol. 3. Permanon Press. p. 438. ISBN 9781483139593.
  3. [3]
    Dillon, K. B.; Craveirinha Dillon, M. G.; Waddington, T. C. (1977). "The identification of some new thiophosphoryl compounds containing P–I bonds by means of 31P N.M.R. spectroscopy". Inorg. Nucl. Chem. Lett. 13 (8): 349–353. doi:10.1016/0020-1650(77)80109-8.
Stub icon

This inorganic compound–related article is a stub. You can help Wikipedia by expanding it.
Share this article:

This article uses material from the Wikipedia article Thiophosphoryl_iodide, and is written by contributors. Text is available under a CC BY-SA 4.0 International License; additional terms may apply. Images, videos and audio are available under their respective licenses.