Involutin

Involutin

Involutin

Chemical compound


Involutin is an organic compound that can be found in mushrooms belonging to the genus Paxillus. It is part of a class of compounds known as diarylcyclopentenones. It is derived from atromentin which was shown from 3′,3″,5′,5″-d4-atromentin (deuterated atromentin) feeding studies and observing the deuterated incorporation into two atromentin derivatives (i.e., an increase in monoisotopic mass by 4 mass units), gyrocyanin and its oxidation product gyroporin.[1] It has been shown to be a Fe3+-reductant and presumed to be involved in Fenton chemistry for the initial attack of dead plant matter.[2]

Quick Facts Names, Identifiers ...

References

  1. Braesel, J; Götze, S; Shah, F; Heine, D; Tauber, J; Hertweck, C; Tunlid, A; Stallforth, P; Hoffmeister, D (2015). "Three Redundant Synthetases Secure Redox-Active Pigment Production in the Basidiomycete Paxillus involutus". Chemistry & Biology. 22 (10): 1325–34. doi:10.1016/j.chembiol.2015.08.016. PMID 26496685.
  2. Shah, F; Schwenk, D; Nicolás, C; Persson, P; Hoffmeister, D; Tunlid, A (2015). "Involutin is an Fe3+ Reductant Secreted by the Ectomycorrhizal Fungus Paxillus involutus during Fenton-Based Decomposition of Organic Matter". Applied and Environmental Microbiology. 81 (24): 8427–8433. doi:10.1128/AEM.02312-15. PMC 4644656. PMID 26431968.



Share this article:

This article uses material from the Wikipedia article Involutin, and is written by contributors. Text is available under a CC BY-SA 4.0 International License; additional terms may apply. Images, videos and audio are available under their respective licenses.