(Cyclopentadienyl)zirconium_trichloride

(Cyclopentadienyl)zirconium trichloride

(Cyclopentadienyl)zirconium trichloride

Chemical compound

(Cyclopentadienyl)zirconium trichloride is an organozirconium compound with the formula (C5H5)ZrCl3. It a moisture-sensitive white solid. The compound adopts a polymeric structure.[1] The compound has been well studied spectroscopically.[2]

Quick Facts Identifiers, Properties ...

Synthesis and reactions

It is prepared by chlorination of zirconocene dichloride.[3] Being polymeric, complex is insoluble in nonpolar solvents. It dissolves in the presence of basic ligands to give adducts.

See also

References

  1. [1]
    Engelhardt, L. M.; Papasergio, R. I.; Raston, C. L.; White, A. H. (1984). "Crystal Structures of Trichloro(η5-cyclopentadienyl)titanium(IV) and -zirconium(IV)". Organometallics. 3: 18–20. doi:10.1021/om00079a005.
  2. [2]
    Rossini, A. J.; Mills, R. W.; Briscoe, G. A.; Norton, E. L.; et al. (2009). "Solid-State Chlorine NMR of Group IV Transition Metal Organometallic Complexes". Journal of the American Chemical Society. 131 (9): 3317–3330. doi:10.1021/ja808390a. PMID 19256569.
  3. [3]
    Gerhard Erker (1990). "Mono(η-cyclopentadienyl)zirconium Complexes: from Coordination Chemistry to Enantioselective Catalysis". Journal of Organometallic Chemistry. 400 (1–2): 185–203. doi:10.1016/0022-328X(90)83012-9.
Share this article:

This article uses material from the Wikipedia article (Cyclopentadienyl)zirconium_trichloride, and is written by contributors. Text is available under a CC BY-SA 4.0 International License; additional terms may apply. Images, videos and audio are available under their respective licenses.