For a pure hydrogen nebula, the ionization equilibrium states that the number per unit time of ionizing photons from the central star has to be balanced by the rate of recombinations of protons and electrons to neutral hydrogen inside the Strömgren sphere of the nebula. Ionizations can only be caused by photons having at least the frequency , corresponding to the ionization potential of hydrogen which is 13.6eV:
Here, is the radius of the Strömgren sphere and are the number densities of protons and electrons, respectively. The luminosity of the central star is denoted by and is the recombination coefficient to the excited levels of hydrogen.
The ratio between the number of photons emitted by the nebula in the Hβ line and the number of ionizing photons from the central star can then be estimated:
where is the effective recombination coefficient for Hβ.
Given a stellar reference frequency , the Zanstra ratio is defined by
with and being the fluxes in the stellar reference frequency and in Hβ, respectively. Using the second formula, the Zanstra ratio can be determined by observations.
On the other hand, applying model stellar atmospheres, theoretical Zanstra ratios may be computed in dependence of the central star's effective temperature which may be fixed by comparison with the observed value of the Zanstra ratio.