Transmittance

Transmittance

Transmittance

Effectiveness of a material in transmitting radiant energy


In optical physics, transmittance of the surface of a material is its effectiveness in transmitting radiant energy. It is the fraction of incident electromagnetic power that is transmitted through a sample, in contrast to the transmission coefficient, which is the ratio of the transmitted to incident electric field.[2]

Earth's atmospheric transmittance over 1 nautical mile sea level path (infrared region[1]). Because of the natural radiation of the hot atmosphere, the intensity of radiation is different from the transmitted part.
Transmittance of ruby in optical and near-IR spectra. Note the two broad blue and green absorption bands and one narrow absorption band on the wavelength of 694 nm, which is the wavelength of the ruby laser.

Internal transmittance refers to energy loss by absorption, whereas (total) transmittance is that due to absorption, scattering, reflection, etc.

Mathematical definitions

Hemispherical transmittance

Hemispherical transmittance of a surface, denoted T, is defined as[3]

where

  • Φet is the radiant flux transmitted by that surface;
  • Φei is the radiant flux received by that surface.

Spectral hemispherical transmittance

Spectral hemispherical transmittance in frequency and spectral hemispherical transmittance in wavelength of a surface, denoted Tν and Tλ respectively, are defined as[3]

where

Directional transmittance

Directional transmittance of a surface, denoted TΩ, is defined as[3]

where

  • Le,Ωt is the radiance transmitted by that surface;
  • Le,Ωi is the radiance received by that surface.

Spectral directional transmittance

Spectral directional transmittance in frequency and spectral directional transmittance in wavelength of a surface, denoted Tν,Ω and Tλ,Ω respectively, are defined as[3]

where

Luminous transmittance

In the field of photometry (optics), the luminous transmittance of a filter is a measure of the amount of luminous flux or intensity transmitted by an optical filter. It is generally defined in terms of a standard illuminant (e.g. Illuminant A, Iluminant C, or Illuminant E). The luminous transmittance with respect to the standard illuminant is defined as:

where:

  • is the spectral radiant flux or intensity of the standard illuminant (unspecified magnitude).
  • is the spectral transmittance of the filter
  • is the luminous efficiency function

The luminous transmittance is independent of the magnitude of the flux or intensity of the standard illuminant used to measure it, and is a dimensionless quantity.

Beer–Lambert law

By definition, internal transmittance is related to optical depth and to absorbance as

where

  • τ is the optical depth;
  • A is the absorbance.

The Beer–Lambert law states that, for N attenuating species in the material sample,

or equivalently that

where

Attenuation cross section and molar attenuation coefficient are related by

and number density and amount concentration by

where NA is the Avogadro constant.

In case of uniform attenuation, these relations become[4]

or equivalently

Cases of non-uniform attenuation occur in atmospheric science applications and radiation shielding theory for instance.

Other radiometric coefficients

More information Quantity, SI units ...

See also


References

  1. "Electronic warfare and radar systems engineering handbook". Archived from the original on September 13, 2001.{{cite web}}: CS1 maint: unfit URL (link)
  2. IUPAC, Compendium of Chemical Terminology, 2nd ed. (the "Gold Book") (1997). Online corrected version: (2006) "Transmittance". doi:10.1351/goldbook.T06484
  3. IUPAC, Compendium of Chemical Terminology, 2nd ed. (the "Gold Book") (1997). Online corrected version: (2006) "Beer–Lambert law". doi:10.1351/goldbook.B00626

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