Methyl_halide

Monohalomethane

The monohalomethanes are organic compounds in which a hydrogen atom in methane is replaced by a halogen. They belong to the haloalkanes or to the subgroup of halomethanes.

Structural formula
Name Fluoromethane
Methyl fluoride
Chloromethane
Methyl chloride
Bromomethane
Methyl bromide
Iodomethane
Methyl iodide
Melting point −137,8 °C[1] −97,4 °C[2] −93,7 °C[3] −66 °C[4]
Boiling point −78,4 °C[1] −23,8 °C[2] 4,0 °C[3] 42 °C[4]
Space-filling model

The four common[lower-alpha 1] members are fluoromethane, chloromethane, bromomethane and iodomethane.

Historical name for this group is methyl halides; it's still widely used. The compounds of this class are often described as CH3X or MeX (X - any halogen, Me - methyl group).

There are analogs with more than one hydrogen atom in methane is replaced by a halogen:

Analogs with carbon atom replaced with a heavier group 14 element are also known:

See also

Notes

  1. Highly radioactive CH3At (methyl astatide) has been detected.[5] The known isotopes of even heavier group 17 element, tennessine, are too short-lived to allow for chemical experimentation.

References

  1. "Chemical Fact Sheet: Astatine". European Virtual Institute for Speciation Analysis (EVISA).



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